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The value may be either positive or negative. Noble gases have significant positive enthalpy in the gain of electrons.Electron Affinity was a concept that was discovered of 1901 in view of the discovery of electron negativity by Linus Carl Pauling. <br> <br>Defining second electron affinity. Flashcards. Fluorine is much more reactive than chlorine (despite the lower electron affinity) because the energy released in other steps in its reactions more than makes up for the lower amount of energy released as electron affinity.Often in their reactions these elements form their negative ions. <br>Each outer electron in effect feels a pull of 7+ from the centre of the atom, irrespective of which element you are talking about.An overall reaction will be made up of lots of different steps all involving energy changes, and you cannot safely try to explain a trend in terms of just one of those steps. <br> <br>A negative electron affinity means energy must be input in order to attach an electron to the ion. <br> When an electron is added to halogens with very high electron affinity, high energy is releasedThe change in energy is negative if a reaction is exothermic. <br> <br>It assumes that you know about simple atomic orbitals, and can write electronic structures for simple atoms.The incoming electron is going to be closer to the nucleus in fluorine than in any other of these elements, so you would expect a high value of electron affinity.The reactivity of the elements in group 7 falls as you go down the group - fluorine is the most reactive and iodine the least.The over-riding factor is therefore the increased distance that the incoming electron finds itself from the nucleus as you go down the group. Addition of an electron to a NEUTRAL atom that can COMPLETE any she'll. <br> <br>It is the energy needed to carry out this change per mole of X-. <br> <br>It increases moving down a column or group and also increases moving from left to right across a row or period (except for the noble gases). At GCSE the impression is sometimes given that the fall in reactivity is because the incoming electron is held less strongly as you go down the group and so the negative ion is less likely to form. Test. Why is the second electron affinity of all atoms positive?How to calculate the value for the second electron affinity of oxygen?The first electron affinity is the energy released when 1 mole of gaseous atoms each acquire an electron to form 1 mole of gaseous -1 ions. <br> <br>The electron affinity trend describes the trend across the periodic table and describes how much energy in an atom is released or spent when an electron is added to a neutral atom or the energy change that occurs when an electron is added to a neutral atom.. ), Gas Phase Ion Chemistry, 2, New York: Academic Press, p. 53. 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